This pairing originated from the episode "Basic Cable". In the episode, Pete goes to Sophie's locker and nervously offers to show her around. He lies about liking Scottsdale when she mentions being from there. While he seems to like her, she seems to have more interest in Scott, and they aren't seen interacting again after Scott shoos him away as he did with the rest of the boys.
Although Pete showing interest in Sophie is shown in the episode, the pairing is not very popular, likely because Scottphie is preferred by most.
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